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Accueil > Equipes de recherche > Chimie Bioinorganique Supramoleculaire > Publications récentes

Publications

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2018
  • Selective EPR detection of primary amines in water with a calix[6]azacryptand-based copper(II) funnel complex,
    A. Inthasot, N. Le Poul, M. luhmer, B. Colasson,* I. Jabin,* O. Reinaud,* Inorg. Chem. 2018,
    ASAP
    .DOI:10.1021/acs.inorgchem.7b0254.

  • Remote electrochemical modulation of pK a in a rotaxane by co-conformational allostery
    G. Ragazzon, C. Schäfer, P. Franchi, S. Silvi, B. Colasson, M. Lucarini, A. Credi, Proc. Natl. Acad. Sci. U.S.A. 2018, https://doi.org/10.1073/pnas.1712783115

2017
  • Mimicking the regulation step of Fe-monooxygenases: Allosteric modulation of Fe(IV)-Oxo formation by guest binding in a dinuclear Zn(II)-Fe(II) calix[6]arene-based funnel complex,
    N. Ségaud, C. De Thomasson, C. Daverat,, K. Sénéchal-David, A. Dos Santos, V. Steinmetz, P. Maître, J.-N. Rebilly,[b],* Frédéric Banse,[a],* Olivia Reinaud, Chem. Eur. J. 2017, 23, 2894-2906. DOI: 10.1002/chem.201605248.

  • Selective Fluorimetric Detection of Primary Alkylamines by a Calix[6]arene Funnel Complex,
    C. Rémy, H. Guyon, J.-N. Rebilly, I. Leray,* O. Reinaud*, Chem. Eur. J. 2017, 23, 8669 –8677. DOI: 10.1002/chem.201700640R1.

  • “Two-story” Calix[6]arene-based Zinc and Copper Complexes: Structure, Properties, O2 Binding,
    G. De Leener, D. Over, C. Smet, D. Cornut, A. Gabriela Porras-Gutierrez, I. Lopez, B. Douziech, N. Le Poul,* F. Topić, K. Rissanen, Y. Le Mest, I. Jabin,* O. Reinaudb,* Inorg. Chem. 2017, in press. DOI: 10.1021/acs.inorgchem.7b01225.


2016

  • Triflate-Functionalized Calix[6]arenes as Versatile Building-Blocks: Application to the Synthesis of an Inherently Chiral Zn(II) Complex
    S. Zahim, R. Lavendomme, O. Reinaud, M. Luhmer, G. Evano, I. Jabin,* Org. Biomol. Chem. 2016, 14, 1950–1957

  • Kinetic and Thermodynamic Stabilization of Metal Complexes by Introverted Coordination in a Calix[6]-azacryptand
    A. Inthasot, E. Brunetti, M. Lejeune, N. Menard, T. Prangé, L. Fusaro, G. Bruylants, O. Reinaud,* M. Luhmer,* I. Jabin*, B. Colasson*, Chem. Eur. J. 2016, 22, 4855 – 4862. DOI : 10.1002/chem.201505057

  • One step synthesis of calix[n]quinones through the HClO4/PbO2 mediated oxidation of calix[n]arenes
    R. Lavendomme, L. Troian-Gautier, S. Zahim, O. Reinaud,* I. Jabin,* Eur. J. O. C. 2016, 1665–1668. DOI: 10.1002/ejoc.201600092

  • Immobilization of monolayers incorporating Cu funnel complexes onto gold electrodes. Application to the selective electrochemical recognition of primary alkylamines in water
    G. De Leener, F. Evoung-Evoung, A. Lascaux, J. Mertens, A. G. Porras-Gutierrez, N. Le Poul,* C. Lagrost, D. Over, Y. R. Leroux, F. Reniers, P. Hapiot, Y. Le Mest, I. Jabin,* O. Reinaud,* J. Am. Chem. Soc. 2016, 138, 12841–12853. DOI: 10.1021/jacs.6b05317.


2015

  • Primary Amine Recognition in Water by a Calix[6]aza-cryptand Incorporated in Dodecylphosphocholine Micelles
    E. Brunetti, A. Inthasot, F. Keymeulen, O. Reinaud, I. Jabin* and K. Bartik*, Org. Biomol. Chem. 2015, 13, 2931–2938. DOI: 10.1039/C4OB02495H

  • The first water-soluble bowl complex: Molecular Recognition of Acetate by the Biomimetic Tris(imidazole) Zn(II) System at pH 7.4.
    S. Rat, J. Gout, O. Bistri, O. Reinaud,* Org. Biomol. Chem., 2015, 13, 3194-3197. DOI: 10.1039/C4OB02514H.

  • Supramolecular assistance for the selective demethylation of calixarene-based receptors,
    Danjou, P. E.; De Leener, G.; Cornut, D.; Moerkerke, S.; Mameri, S.; Lascaux, A.; Wouters, J.; Brugnara, A.; Colasson, B.; Reinaud, O.*; Jabin, I.* J. Org. Chem. 2015, 80, 5084–5091.


2014
  • A Water-Soluble Calix[4]arene-Based Ligand for the Selective Linear Coordination and Stabilization of Copper(I) Ion in Aerobic Conditions
    Maurin, Antoine; Varatharajan, Sambika; Colasson, Benoit; Reinaud, Olivia
    Org. Lett. 2014, 16, 5426-5429.

  • A versatile strategy for appending a single functional group to a multifunctional host through host-guest covalent-capture
    Jean-Noël Rebilly, Assia Hessani, Benoit Colasson, and Olivia Reinaud
    Org. Biomol. Chem. 2014, 12, 7780-7785.

  • Selective recognition of fluoride anion in water by a copper(II) center embedded in a hydrophobic cavity
    Andrea Brugnara, Filip Topić, KariRissanen, Aurélien de la Lande, Benoit Colasson and Olivia Reinaud
    Chem. Sci. 2014, 5, 3897 - 3904.

  • One-Pot Electrografting of Mixed Mono-Layers with Controlled Composition
    Luis Miguel Santos, Alice Mattiuzzi, Ivan Jabin, Nicolas Vandencasteele, Francois Reniers, Olivia Reinaud, Philippe Hapiot, SébastienLhenry, Yann R Leroux, and Corinne Lagrost
    J. Phys. Chem. C 2014, 29, 15919-15928.

  • Supramolecular Control of a Mononuclear Biomimetic Copper(II) center: Bowl Complexes vs. Funnel Complexes
    J. Gout, A.Višnjevac, S. Rat, A. Parrot, A.Hessani, O. Bistri, N. Le Poul, Y. Le Mest, O. Reinaud
    Eur. J. Inorg. Chem. 2014, 2819-2828.

  • Locally induced and self-induced “electro-click” onto self-assembled monolayer by SECM under unbiased conditions
    Sébastien Lhenry, Yann R. Leroux, Christophe Orain, Francoise Conan, Nathalie Cosquer, Nicolas Le Poul, Yves Le Mest, Olivia Reinaud, Philippe Hapiot
    Langmuir 2014, 30, 4501-4508.

  • An induced-fit process through mechanical pivoting of aromatic walls in host-guest chemistry of calix[6]areneaza-cryptands
    Andrea Brugnara, Luca Fusaro, Michel Luhmer, Thierry Prangé, Benoit Colasson, Olivia Reinaud
    Org. Biomol. Chem. 2014, 12, 2754-2760.

  • Insights into water coordination associated to the CuII/CuI electron transfer at a biomimetic Cu centre
    A. Gabriel Porras Gutiérrez, J. Zeitouny, A. Gomila, B. Douziech, N. Cosquer, F. Conan, O. Reinaud, P. Hapiot, Y. Le Mest, C. Lagrost, N. Le Poul
    Dalton Trans. 2014, 43, 6436 - 6445.

  • Supramolecular assistance for the selective mono-functionalization of a calix[6]arenetris-carboxylic acid based receptor
    Alex Inthasot, Minh-Dung Dang Thy, Manuel Lejeune, Luca Fusaro, Olivia Reinaud, Michel Luhmer, Benoit Colasson, Ivan Jabin
    J. Org. Chem. 2014, 79, 1913-1919.

  • Revues
  • Calixarenes and resorcinarenes as scaffolds for supramolecularmetallo-enzyme mimicry, J.-N. Rebilly, O. Reinaud,
    Supramol. Chem. (special issue “calix13”), 2014, 26, 454-479. DOI: 10.1080/10610278.2013.877137


2013

  • Iron Coordination Chemistry with New Ligands Containing Triazole and Pyridine Moieties. Comparison of the Coordination Ability of the N-donors
    Ségaud, N., Rebilly, J.N., Sénéchal-David, K., Guillot, R., Billon, L., Reinaud, O., Banse, F.
    Inorg. Chem. , 2013, 52, 691-700.

  • Guest-Triggered ZnII Translocation and Supramolecular Nuclearity Control in Calix[6]arene-Based Complexes
    Bernier, N., Menard, N., Colasson, B., Rebilly, J.N., Reinaud, O.
    Inorg. Chem. , 2013, 52, 4683-4691.

  • Electrochemically-driven cup-and-ball copper complexes
    Menard, N., Hériot, Y., Le Mest, Y., Reinaud, O., Le Poul, N., Colasson, B.
    Chem. Eur.J. , 2013, 19, 10611-10618.

  • Bowl vs. Funnel supramolecular concept for Cu(I) Complexes within the Biomimetic Tris-imidazole Core
    Gout, J., Višnjevac, A., Rat, S., Bistri, O., Le Poul, N., Le Mest, Y., Reinaud, O.
    Eur.J.I.C. , 2013, 5171-5180.

  • Investigation of the Hydroxylation Mechanism of Noncoupled Copper Oxygenases by Ab Initio Molecular Dynamics Simulations
    Melia, C., Ferrer, S., Řezáč, J., Parisel, O., Reinaud, O., Moliner, V., de la Lande, A.
    Chem. Eur. J. , 2013, 19, 17328-17337.

  • Coordination of Lead(II) in the Supramolecular Environment Provided by a “Two-Story” Calix[6]arene-based N6 Ligand
    Over, D., Zeng, X., Bornholdt, C., Marrot, J., Reinaud, O.
    Inorg. Chem. , 2013, 52, 14089-14095.

  • Proton-induced motion in a molecular cup-and-ball Zinc funnel complex
    Menard,N., Over, D., Reinaud, O., Colasson, B.
    Tet. Lett. , 2013, 54, 3398-3401.

  • Guest Covalent Capture by a Host : A Biomimetic Strategy for the Selective Functionalization of a Cavity
    Menard, N. ; Reinaud, O. ; Colasson, B.
    Chem. Eur. J. , 2013, 19, 641-652.


2012

  • Electrografting of calix[4]arenediazonium salts to form versatile robust platforms for spatially controlled surface functionalization,
    Mattiuzzi, A. ; Jabin, I. ; Mangeney, C. ; Roux, C. ; Reinaud, O. ; Santos, L. ; Bergamini, J.F. ; Hapiot, P. ; Lagrost, C.
    Nature Comm., 2012, DOI : 10.1038/ncomms2121.
  • Ipso-nitration of calix[6]azacrytands : Intriguing effects of the small rim capping pattern on the large rim substitution selectivity,
    Lejeune, M. ; Picron, J.-F. ; Mattiuzzi, A. ; Lascaux, A. ; De Cesco, S. ; Brugnara, A. ; Thiabaud, G. ; Darbost, U. ; Colasson, B. ; Reinaud, O. and Jabin, I.
    J. Org. Chem., 2012, 77, 3838-3845.
  • Supramolecular control of hetero-multinuclear polytopic binding of metal ions (ZnII, CuI) at a single calix[6]arene-based scaffold,
    Rebilly, J. N. ; Bistri, O. ; Colasson, B. and Reinaud, O.,
    Inorg. Chem., 2012, 51, 5965-5974.
  • Synthesis and studies of a water-soluble and air-stable CuI/CuII open-shell funnel complex, Thiabaud, G. ; Brugnara, A. ; Carboni, M. ; Le Poul, N. ; Colasson, B. ; Le Mest, Y. and Reinaud, O., Org. Lett., 2012, 14, 2500-2503.
  • Recognition of Primary Amines in Water by a Zinc Funnel Complex Based on Calix[6]arene, Olivia Bistri, Benoit Colasson and Olivia Reinaud,
    Chem. Sci., 2012, 3, 811-818.

2011

  • Synthesis of “Two-Story” Calix[6]aza-Cryptands
    Xianshun Zeng, Claudia Bornholdt, Diana Over, Olivia Reinaud,
    Org. Lett., 2011, 13, 5660-5663.
  • Tris(triazolyl) Calix[6]arene-Based Zinc and Copper Funnel Complexes : Imidazole-like or Pyridine-like ? A Comparative Study
    Benoit Colasson, Nicolas Le Poul, Yves Le Mest and Olivia Reinaud,
    Inorg. Chem. 2011, 50, 10985-10993.
  • Calorimetric Study on Coordination of Tridentate Imidazolyl Calix[6]arene Ligands to Zinc Ion in Organic Solvents
    Koji Kano, Masataka Kondo, Haruka Inoue, Hiroaki Kitagishi, Benoit Colasson, and Olivia Reinaud, Inorg. Chem. 2011, 50, 6353-6360.
  • Allosterically driven self-assemblies of interlocked calix[6]arene receptors
    Stéphane Le Gac, Jean-François Picron, Olivia Reinaud and Ivan Jabin
    Org. Biomol. Chem, 2011, 9, 2387-2396.
  • Synthesis and first studies of the host-guest and substrate recognition properties of a porphyrin tethered calix[6]arene ditopic ligand,
    Cyrille Monnereau, Jean- Noël Rebilly, and Olivia Reinaud,
    Eur. J. Org. Chem. 2011, 166-175.

2010

  • Self-induced "electroclick" immobilization of a copper complex onto self-assembled monolayers on a gold electrode,
    Antoine Gomila, Nicolas Le Poul, Nathalie Cosquer, Jean-Michel Kerbaol, Jean-Marc Noël, Madhusudana T. Reddy, Ivan Jabin, Olivia Reinaud, Francoise Conan and Yves Le Mest,
    Dalton Trans. 2010, 39, 11516-11518.

  • First ZnII Bowl-Complexes Modeling the Tris(histidine) Metallo-Site of Enzymes,
    Aleksandar Visˇnjevac, Jérôme Gout, Nicolas Ingert, Olivia Bistri, and Olivia Reinaud,
    Org. Lett. 2010, 12, 2044-2047.

  • Electrochemically Triggered Double Translocation of Two Different Metal Ions With a Ditopic Calix[6]arene Ligand,
    Benoit Colasson, Nicolas Le Poul, Yves Le Mest, and Olivia Reinaud,
    J. Am. Chem. Soc. 2010, 132, 4393-4398.

  • Spontaneous formation of vesicles in a catanionic association involving a head and tail functionalized amino-calix[6]arene,
    C. Bize, J.-C. Garrigues, M. Blanzat, I. Rico-Lattes, O. Bistri, B. Colasson, O. Reinaud,
    Chem. Commun. 2010, 46, 586 - 588.


2009
  • Mimicking the Protein Access Channel to a Metal Center : Effect of a Funnel-Complex on Dissociative vs Associative Copper Redox Chemistry,
    N. Le Poul, B. Douziech, J. Zeitouny, G. Thiabaud, H. Colas, F. Conan, N. Cosquer, I. Jabin, C. Lagrost, P. Hapiot, O. Reinaud, and Y. Le Mest,
    J. Am. Chem. Soc. 2009, 131, 17800-17807.

  • Solid State Chemistry at an Isolated Cu(I) Center with O2,
    G. Thiabaud, G. Guillemot, I. Schmitz-Afonso, B. Colasson, O. Reinaud,
    Angew. Chem. Int. Ed. 2009, 48, 7383-7386.

  • Directional Control and Supramolecular Protection with a Ditopic Calix[6]arene-based Funnel Complex,
    D. Coquière, A. de la Lande, O. Parisel, T. Prangé and O. Reinaud,
    Chem. Eur. J. , 2009, 15, 11912 - 11917.

  • Biomimetic and self-assembled calix[6]arene-based receptors for neutral molecules
    D. Coquière, S. Le Gac, U. Darbost, O. Sénèque, I. Jabin, O. Reinaud,
    Org. Biomol. Chem., 2009, 7, 2485-2500 (Perspective).

  • Replacement of a nitrogen by a phosphorous donor in biomimetic copper complexes : a surprising but informative case study with calix[6]arene-based cryptands.
    D. Over, A. de la Lande, X. Zeng, O. Parisel, O. Reinaud,
    Inorg. Chem. 2009, 48, 4317-4330.

  • Multipoint molecular recognition within a calix[6]arene funnel complex (Special Feature)
    D. Coquière, A. de la Lande, S. Martí, O. Parisel, T. Prangé and O. Reinaud,
    Proc. Natl. Acad. Sci. USA, 2009, 106, 10449-10454.

  • Evidence for a tritopic “mono” basic site within a calix[6]arene funnel complex. Application to multipoint molecular recognition,
    D. Coquière, A. de la Lande, S. Martí, O. Parisel, T. Prangé and O. Reinaud,
    Proc. Natl. Acad. Sci. USA, 2009, 106, 10449-10454.


2008
  • Selective Hetero-Trisfunctionalization of the Large Rim of a Biomimetic Calix[6]arene Using Host-Guest Chemistry as a Synthetic Tool.
    B. Colasson and O. Reinaud,
    J. Am. Chem. Soc. 2008, 130, 15226-15227.

  • Spectacular Induced-Fit Process for Guest Binding by a Calix[6]arene Zn(II) Funnel Complex,
    D. Coquière, J. Marrot, O. Reinaud,
    Org. Biomol. Chem. 2008, 6, 3930-3934.

  • Dioxygen Activation at a Mononuclear Cu(I) Center Embedded in the Calix[6]arene-Tren Core. G. Izzet, J. Zeitouny, H. Akdas-Killig, Y. Frapart, S. Ménage, B. Douziech, I. Jabin, Y. Le Mest, O. Reinaud,
    J. Am. Chem. Soc. 2008, 130, 9514-9523.

  • Theoretical exploration on the oxidative properties of a [(tren)CuO2]+ adduct relevant to monooxygenase enzymes : insights into the competitive deshydrogenation vs. hydroxylation reactive pathways.
    A. de la Lande, O. Parisel, H. Gérard, V. Moliner, O. Reinaud,
    Chem. Eur J. 2008, 14, 6465-6473.


2007

  • "A Ditopic Calix[6]arene Ligand with N-Methyl-Imidazole and 1,2,3-Triazole Substituents : Synthesis and Coordination with Zn(II) Cations. "
    Benoit Colasson, Marion Save, Petr Milko, Jana Roihová, Detlef Schröder, and Olivia Reinaud,
    Org. Lett. 2007, 9, 4987-4990.

  • "Innovative Methodologies for the N-Protection of N-Alkylimidazole Groups : Application to the First Synthesis of a Water-Soluble Calix[6]arene Presenting Three Ammonium Substituents at the Large Rim and Three Neutral N-Donors at the Small Rim."
    Coquiere, D. ; Marrot, J. ; Reinaud, O.,
    Org. Lett. 2007, 9, 3271-3274.

  • "Self-assembly via ionic interactions of calix[6]arene based receptors displaying remarkable host-guest properties toward neutral guests."
    Stéphane Le Gac, Michel Luhmer, Olivia Reinaud and Ivan Jabin,
    Tetrahedron 2007,63, 10721-10730.

  • Cover : Tetrahedron 63/2007.
  • "Mono-Copper Center Embedded in a Biomimetic Cavity : from Supramolecular Control of Copper Coordination to Redox Regulation"
    Nicolas Le Poul, Morgan Campion, Bénédicte Douziech, Yannick Rondelez, Loïc Le Clainche, Olivia Reinaud, Yves Le Mest,
    J. Am. Chem. Soc. 2007, 129, 8801-8810.

  • "Architecture-Controlled “Smart” Calix[6]arene Self-Assemblies in Aqueous Solution"
    S. Houmadi, D. Coquière, L. Legrand, M.-C. Fauré, M. Goldmann, O. Reinaud and S. Rémita
    Langmuir, 2007,23, 4849 - 4855.

  • "Insights into the Binding Properties of a Cuprous Ion Embedded in the Tren Cap of a Calix[6]arene and Supramolecular Trapping of an Intermediate"
    G. Izzet, M.-N. Rager, O. Reinaud,
    Dalton Trans. 2007, 771 - 780.

  • "First insights into the electronic properties of a Cu(II) center embedded in the PN3 cap of a calix[6]arene-based ligand."
    G. Izzet, X. Zeng, D. Over, B. Douziech, J. Zeitouny, M. Giorgi, I. Jabin, Y. Le Mest, O. Reinaud,
    Inorg. Chem. 2007 375-377.

  • "Drastic effects of the second coordination sphere on neutral vs. anionic guest binding to a biomimetic Cu(II) center embedded in a calix[6]aza-cryptand"
    G. Izzet, X. Zeng, H. Akdas, J. Marrot and O. Reinaud,
    Chem Commun. 2007, 810-812.

  • "Tuning of the Intra-Cavity Binding Properties of a Calix[6]arene by the External Binding to a Zn(II) Center Coordinated to Amino Arms,"
    U. Darbost, O. Sénèque, Y. Li, G. Bertho, J. Marrot, M.-N. Rager, O. Reinaud, I. Jabin,
    Chem. Eur. J. 2007, 13, 2078-2088.

Till 2006

  • "Encapsulation of a (H3O2)– unit in the aromatic core of a calix[6]arene closed by two Zn(II) ions at the small and large rims,"
    D. Coquière, J. Marrot and O. Reinaud,
    Chem. Commun. 2006 3924-3926.

  • "Efficient Synthesis of Calix[6]tmpa : a New Calix[6]aza-cryptand with Original Conformational and Host-Guest Properties"
    X. Zeng, D. Coquière, A. Alenda, E. Garrier, T. Prangé ;, Y. Li, O. Reinaud, I. Jabin,
    Chem. Eur. J. 2006, 12, 6393-6402.

  • "Theoretical modelling of tripodal CuN3 and CuN4 cuprous complexes interacting with O2, CO or CH3CN "
    A. de la Lande,H. Gérard,V. Moliner,G. Izzet, O. Reinaud, O. Parisel
    J. Biol Inorg. Chem. 2006,593-608.

  • "Allosterically Coupled Double Induced Fit for a 1+1+1+1 Self-assembly of a Calix[6]tris-amine, a Calix[6]tris-acid and their Respective Guest"
    S. Le Gac, J. Marrot, O. Reinaud, and I. Jabin,
    Angew. Chem. Int. Ed. 2006, 45, 3123-3126

  • Ipso-Chlorosulfonylation of Calixarenes: a Powerful Tool for the Selective Functionalization of the Large Rim,
    D. Coquière, H. Cadeau, Y. Rondelez, M. Giorgi and O. Reinaud
    J. Org. Chem. 2006, 71, 4059-4065

  • "Supramolecular Assemblies with Calix[6]arenes and Copper Ions : From Dinuclear to Trinuclear Linear Arrangements of Hydroxo-Cu(II) Complexes"
    G. Izzet, H. Akdas, N. Hucher, M. Giorgi, T. Prangé, O. Reinaud,
    Inorg. Chem. 2006, 45, 1069-1077.

  • "X-ray diffraction and EXAFS Studies of Hydroxo-Cu(II) Complexes Based on a Calix[6]arene-N3 Ligand : Evidences for a Mono-nuclear/Dinuclear Equilibrium Controlled by Supramolecular Features"
    G. Izzet , Y. M. Frapart, T. Prangé, K. Provost, A. Michalowicz, O. Reinaud,
    Inorg. Chem., 2005, 44, 9743-9751.

  • "Biomimetic Zinc Funnel Complexes Based on Calix[6]N3ArO Ligands : an Acid-Base Switch for Guest Binding."
    O. Sénèque, M.-N. Rager, M. Giorgi, T. Prangé, A. Tomas, and O. Reinaud.
    J. Am. Chem. Soc. 2005, 127, 14833-14840.

  • "Polarizing a Hydrophobic Cavity for the Efficient Binding of Organic Guests : the Case of Calix[6]tren, a Highly Efficient and Versatile Receptor for Neutral or Cationic Species."
    U. Darbost, M.-N. Rager, S. Petit, I. Jabin and O. Reinaud,
    J. Am. Chem. Soc .2005, 127, 8517 - 8525

  • "Calix[6]tren and Copper(II) : A Third Generation of Funnel Complexes on the Way to Redox Calix-zymes. "
    G. Izzet, B. Douziech, T. Prangé, A. Tomas, I. Jabin, Y. Le Mest, and O. Reinaud,
    Proc. Natl. Acad. Sci. USA , 2005, 102, 6831-6836.

  • "Electrochemical Behavior of the Tris(Pyridine)-Cu Funnel Complexes : an Overall Induced-Fit Process Involving an Entatic State through a Supramolecular Stress."
    N. Le Poul, M. Campion, G. Izzet, B. Douziech, O. Reinaud, and Y. Le Mest,
    J. Am. Chem. Soc .2005, 127, 5280-5281.

  • "Synthesis and Conformational Study of the First Triply-bridged Calix[6]azatubes. "
    S. Le Gac, X. Zeng, O. Reinaud and I. Jabin,
    J. Org. Chem., 2005, 70, 1204-1210.

  • "A Calix[6]arene Receptor Rigidified by a Self-assembled Tri-ammonium Cap : X-ray and NMR Characterization of the Binding of Polar Neutral Guests"
    U. Darbost, M. Giorgi, N. Hucher, I. Jabin, and O. Reinaud,
    Supramol. Chem . 2005, 17, 243-250.

  • "X-ray and Solution Structure of the First Zn Funnel Complex Based on a Calix[6]aza-cryptand."
    U. Darbost, Xianshun Zeng, M.-N. Rager, M. Giorgi, I. Jabin, and O. Reinaud,
    Eur. J. Inorg. Chem. 2004, 4371-4374.

  • "A Novel Receptor Based on a C3v-Symmetrical PN3-calix[6]cryptand".
    Xianshun Zeng, Nicolas Hucher, Olivia Reinaud and Ivan Jabin,
    J. Org. Chem., 2004, 69, 6886-6889.

  • "An efficient route to disymmetrically substituted calix[6]arenes. Synthesis of novel ligands presenting
    a N2S or N3CO2- binding core. "

    Y. Rondelez, Y. Li and O. Reinaud,
    Tetrahedron Lett . 2004, 45, 4669-4672.

  • "A Novel C3v-Symmetrical Calix[6](aza)cryptand with a Remarkably High and Selective Affinity for
    Small Ammoniums"
    Ulrich Darbost,Michel Giorgi,Olivia Reinaud and Ivan Jabin,
    J. Org. Chem., 2004, 69, 4879-4883
    Couverture : J. Org. Chem. 2004, 69.

  • "Funnel complexes with Co(II) and Ni(II) : new probes into the biomimetic coordination ability of the calix[6]arene-based tris(imidazole) system."
    O. Sénèque, M. Campion, M. Giorgi, Y. Le Mest, O. Reinaud,
    Eur. J. Inorg. Chem. 2004, 1817-1826.
    Cover : Eur. J. Inorg. Chem. 9/2004 (p 1775)

  • "Supramolecular control of an organic radical coupled to a metal ion embedded at the entrance of a hydrophobic cavity"
    O. Sénèque, M. Campion, B. Douziech, M. Giorgi, Y. Le Mest, O. Reinaud
    Dalton Trans. 2003, 4216 - 4218.

  • Classé : « hot paper »
  • "Unprecedented Selective ipso-Nitration of Calixarenes Monitored by the O-Substituents"
    S. Redon, Y. Li, O. Reinaud
    J. Org. Chem. 2003, 68, 7004-7008.

  • "Selective functionalization at the small rim of calix[6]arene. Synthesis of novel non-symmetrical N3, N4 and N3ArO biomimetic ligands"
    O. Sénèque, O. Reinaud,
    Tetrahedron ,2003, 59, 5563-5568.

  • "Bio-inspired calix[6]arene-zinc funnel complexes"
    O. Sénèque, M. Giorgi, O. Reinaud,
    Supramol. Chem., 2003, 15, 573-580.

  • "First C3v-symmetrical Calix[6](aza)crown."
    I. Jabin and O. Reinaud,
    J. Org. Chem. , 2003, 68, 3416-3419.

  • "Supramolecular Assembly with Calix[6]arene and Copper Ions : Formation of a Novel Tetranuclear Core Exibiting Unusual Redox Properties and Catecholase Activity"
    O. Sénèque, E. Rivière, Y. Journaux, Y. Le Mest, O. Reinaud,
    Eur. J. Inorg. Chem., 2002, 2007-2014.

  • "The First Water-Soluble Copper(I) Calix[6]arene Complex presenting a hydrophobie ligand binding pocket : a remarkable model for active sites in metalloenzyme"
    Y. Rondelez, G. Bertho, O. Reinaud,
    Angew. Chem. Int. Ed., 2002, 41, 1044-1046.

  • "Calix[6]arene-based cuprous « funnel complexes : a mimic for the substrate access channel to metallo-enzyme active sites"
    Rondelez, M.-N. Rager, A. Duprat, O. Reinaud,
    J. Am. Chem. Soc., 2002, 124, 1334-1340.

  • "Supramolecular Stabilization of a Tris(imidazolyl) Zn-Aqua Complex Evidenced by X-ray Analysis. A Structural Model for Mono-Zinc Active Sites of Enzymes"
    O. Sénèque, M.-N. Rager, M. Giorgi, O. Reinaud,
    J. Am. Chem. Soc . 2001, 123, 8442-8443.

  • "Calix[6]arene-based N3-donors : a versatile supramolecular system with tunable electronic and steric properties. Study on the formation of tetrahedral dicationic zinc complexes in a biomimetic environment"
    O. Sénèque, Y. Rondelez, L. Le Clainche, C. Inisan, M.-N. Rager, Michel Giorgi, O. Reinaud,
    Eur. J. Inorg. Chem., 2001, 2597-2604.

  • "Hydrogen bonding and CH/ interactions for the stabilization of biomimetic zinc complexes : first examples of X-ray characterized alcohol and amide adducts to a tetrahedral dicationic Zn center"
    O. Sénèque, M. Giorgi, O. Reinaud,
    Chem. Commun . 2001, 984-985.

  • "Calix[6]arene-Based Models for Mono-Copper Enzymes : a Promising Supramolecular System for Oxidation Catalysis"
    L. Le Clainche, Y. Rondelez, Olivier Sénèque, S. Blanchard, M. Campion, M. Giorgi, A. F. Duprat, Y. Le Mest, O. Reinaud
    Comptes Rendus Acad. Sci., Chimie, Série IIc , 2000, 3, 811-819.

  • "Novel Biomimetic Calix[6]arene-based Copper(I)-CO Complexes : a structural and dynamic study"
    Y. Rondelez, O. Sénèque, M.-N. Rager, A. Duprat, O. Reinaud,
    Chem. Eur. J., 2000, 6, 4218-4226.

  • "Novel Biomimetic Calix[6]arene-based Copper(II) Complexes"
    L. Le Clainche, M. Giorgi, O. Reinaud,,
    Inorg. Chem., 2000, 39, 3436-3437.

  • "Calix[6]arenes and Zinc : Novel Biomimetic Receptors For Neutral Molecules"
    O. Sénèque, M.-N. Rager, M. Giorgi, O. Reinaud,
    J. Am. Chem. Soc., 2000, 122, 6183-6189.

  • "A novel calix[4]arene-based two-coordinate copper(I) complex that is strongly resistant to O2"
    L. Le Clainche, M. Giorgi, O. Reinaud,
    Eur.J. Inorg. Chem ., 2000, 1931-1933.

  • "A novel calix[6]arene-based mononuclear copper(I) complex that exhibits chirality at low temperature"
    S. Blanchard, M.-N. Rager A. F. Duprat et O. Reinaud,
    New J. Chem., 1998, 1143-1146.

  • "Calixarene-based Copper(I) Complexes as New Models for Monocopper Sites in Enzymes"
    S. Blanchard, L. Le Clainche, M.-N. Rager, B. Chansou, J. P. Tuchagues, A. Duprat, Y. Le Mest, O. Reinaud,
    Angew. Chem., Int. Ed., 1998, 37, 2732-2735.


Former publications

Former publications :


Synthesis of benzoquinones


"Première synthèse totale d'une hydroxy-méthoxy-quinone : la dihydromaesanine"

O. Reinaud, P. Capdevielle, M. Maumy,

Tetrahedron Lett. 1986, 26, 3993-3996.


"Synthesis of new bicyclic quinones : 2H,1-benzopyran-5,8-quinones and related compounds"

O. Reinaud, P. Capdevielle, M. Maumy,

Synthesis 1987, 790-794.


"Nouvelle transposition acido-catalysée de dialcoxy-orthobenzoquinones"

O. Reinaud, P. Capdevielle, M. Maumy,

Tetrahedron, 1987, 43, 4161-4164.


"Nouvelles voies de synthèse de benzoquinones hétérocycliques"

O. Reinaud, P. Capdevielle, M. Maumy,

Tetrahedron Lett. 1987, 28, 4675-4678.


"Synthesis of new 3-alkenyl-2-hydroxy-5-methoxy-1,4-benzoquinones via Claisen rearrangement of original 4-allyloxy-5-methoxy-1,2-benzoquinones"

O. Reinaud, P. Capdevielle, M. Maumy,

Synthesis 1988, 293-300.


"Synthesis of tetrahydroazocino- and dihydroazepino-1,2-benzoquinones via amino-Claisen rearrangement of 4-(2-vinyl-azetidino and aziridino)-1,2-benzoquinones"

L. Viallon, O. Reinaud, P. Capdevielle, M. Maumy,

Tetrahedron Lett. 1995, 36, 4787-4791.


"Synthesis of new 4-alkylamino-5-methoxy-2H-pyran-2-ones"

L. Viallon, O. Reinaud, P. Capdevielle, M. Maumy,

Tetrahedron Lett. 1995, 36, 6669-6673.


"Synthesis of 5-Alkoxy-4-Alkylamino-1,2-Benzoquinones"

Loïk Viallon, O. Reinaud, P. Capdevielle, M. Maumy,

Synthesis 1995, 1534-1538.


"Reactions of 4-dialkylamino-5-methoxy-1,2-benzoquinones in acidic media: selective C-alkylation or N-dealkylation"

L. Viallon, O. Reinaud, P. Capdevielle, M. Maumy,

Tetrahedron 1996, 52, 7841-7854.


"Thermal and Acid-catalized sigmatropic rearrangements of allylamino-methoxy-1,2-benzoquinones”

L. Viallon, O. Reinaud, P. Capdevielle, M. Maumy,

Tetrahedron 1996, 52, 13605-614.


Patent : "Alkoxy-5-amino-4-benzoquinones-1,2, leur procédé de préparation et compositions pharmaceutiques et cosmétiques les contenant"

L. Viallon, O. Reinaud, P. Capdevielle, M. Maumy, brevet Sanofi-Elf Aquitaine, no 9107735, 1991.




Oxidative metabolism


"Oxidative metabolism of Linoleic Acid by human leukocytes"

O. Reinaud, M. Delaforge, J.L. Boucher, F. Rocchiccioli, D. Mansuy,

Biochem. Biophys. Res. Commun. 1989, 883-886.



Copper-mediated oxidation of aromatic compounds


"Copper(II) mediated aromatic hydroxylation by trimethylamine N-oxide"

O. Reinaud, P. Capdevielle, M. Maumy,

Chem. Commun. 1990, 566-567.


"New and efficient conversion of benzoic acids into salicylic acids via copper-mediated hydroxylation process"

O. Reinaud, P. Capdevielle, M. Maumy,

Synthesis 1990, 612.


"2-(N-amido)-4-nitrophénol: a new ligand for the copper-mediated hydroxylation of aromatics by trimethylamine N-oxide"

O. Reinaud, P. Capdevielle, M. Maumy,

J. Mol. Catal. 1991, 68, L13-16.


"Ortho-aryloxylation of N-substituted benzamides: a new oxidizing process induced by the copper(II)/trimethylamine N-oxide system"

O. Reinaud, P. Capdevielle, M. Maumy,

J. Chem. Soc., Perkin trans. 1991, 2129.



Tris-pyrazolyl borate Co / O2 complexes


"Hydridotris(3-isopropyl-5-methylpyrazolyl)borato]-iodocobalt(II): unusual purification by inverse recrystallization"

O. Reinaud, A. Rheingold, K. H. Theopold,

Inorg. Chem. 1994, 2306-2308.


"Hydrogen tunneling in the activation of dioxygen by a tris(pyrazolyl)borate Cobalt complex"

O. Reinaud, K. H. Theopold,

J. Am. Chem. Soc. 1994, 116, 6979-6980.



"Novel structure of a binuclear cobalt dioxygen complex on the path to dioxygen activation"

O. Reinaud, G. Yap, A. L. Rheingold, K. H. Theopold,

Angew. Chem. Int. Ed. 1995, 34, 2051-2052.



"Can spin state change slow organometallic reactions?”

J. L. Dietrich, O. Reinaud, A. L. Rheingold, K. H. Theopold,

J. Am. Chem. Soc. 1995, 117, 11745-11748.


Dioxygen activation with sterically hindered tris(pyrazolyl)borate cobalt complexes”

K.H. Theopold, O.M. Reinaud, D. Dorena and R. Konecny,

Studies in Surface Science and Catalysis 1997, 110, 1081-108.( Proceedings of the 3rd World Congress on Oxidation Catalysis)


" Toward Benign Synthesis Via Catalytic Oxidations Using Dioxygen or Nitrous Oxide".

Theopold K. H., Reinaud O. M., Blanchard S., Leelasubcharoen S., Hess A., Thyagarajan S.,

in Advancing Sustainability through Green Chemistry; Anastas, P. T.; Lankey, R. L., Eds.; ACS Symposium Series 823; 2002, p. 75-85.